Abstract
Dyestuffs removal from industrial wastewater requires special advanced technologies, since dyes are usually difficult to remove by biological methods. In this study nanofiltration process was used for removal of different dyestuffs from solutions. The rate of dye removal by spiral wound nanofiltration membrane in film thin composite MWCO=90 Dalton, was evaluated for four classes of dyes acidic, disperse, reactive and direct in red and blue dyes medium. Dye absorbance was measured by spectrophotometric method (2120 Standard Method 1998). Effects of feed concentration, pressure and total dissolved solids concentration were also studied. Results showed that increasing dye concentration lead to higher color removal up to 98 % and at different pressures for acidic and reactive blue were up to 99.7 %. Different types of dyes had no effect on dye removal and permeate flux. During 2 h. of the operation time, permeate flux decline was increased. Permeate fluxes for different types of red dyes were from 16.6 to 12.6 (L/m2/h.) and for blue dyes were from 16.6 to 10.45 (L/m2/h.). Presence of sodium chloride in dye solutions increased dye rejections nearby 100 %. Chemical oxygen demand removal efficiencies for reactive blue, disperse blue, direct and disperse red dyes were also approximately 100 %.
Similar content being viewed by others
References
Ahmad, A. L. W.; Puasa, S. M. D.; Zulkali, M., (2006). Micellar-enhanced ultrafiltration for removal of reactive dyes from an aqueous solution, Desalination, 191(1–3), 153–161.
Akbari, A.; Remigy, J. C.; Aptel, P., (2002). Treatment of textile dye effluent using a polyamide-based nanofiltration membrane, Chemi. Eng. Processing, 41(7), 601–609.
AL Bastaki, N.; AL Aseeri, M.; Bu Ali, Q.; Haji, S., (2007). Removal of Acid red and Sodium Chloride mixtures from aqueous solutions using nanofiltration., Desalination., 206(1–3), 407–413.
Carbal Goncalves, I.; Gomes, C. A.; de Pinho, N. M., (2005). The role of adsorbtion on nanofiltration of azo dyes, J. Membrane Sci. 255(1-2), 157–165.
Chaudhari, S.; Manu, B., (2002). Anaerobic decolorisation of simulated textile wastewater containing azo dyes, Bioresource Tech., 82(3), 225–231.
Chen, V.; Tang, C., (2002). Nanofiltration of textile wastewater for water reuse. Desalination, 1 43(1–3), 11–20.
Cho, J.; Amy, G.; Pellegrino, J., (1999). Membrane filtration of natural organic matter: initial comparison of rejection and flux decline characteristics with ultrafiltration and nanofiltration membranes. Water Res., 33(11 ), 2517–2526.
Clesceri, L. S.; Greenberg, A. E.; Eaton, A. D., (1998). Standard Methods for the Examination of Water and Wastewater, 20th Ed., American Public Health Association (APHA), American Water Works Association (AWWA), Water Environment Federation (WEF), United State of America
Das Gupta, S.; Chakraborty, S.; Purkait, K. M.; De, S.; Basu, K. J., (2003). Nanofiltration of textile plant effluent for color removal and reduction in COD. Sep. Purif. Tech., 31(2), 141–151.
DasGupta, S.; Auddy, K.; De, S., (2004), Flux enhancement in nanofiltration of dye solution using turbulent promoters, Sep. Purif. Tech., 40(1), 31–39.
De, S.; Chakraborty, S.; Bag, B. C.; Das Gupta, S.; Basu, K. J., (2004). Prediction of permeate flux and permeate concentration in nanofiltration of dye solution. Sep. Purif. Tech., 35(2), 141–152.
Fuchs, W.; Brike, M.; Schoeberl, P.; Chamam, B.; Braun, R., (2006). Advanced treatment of textile wastewater towards reuse using a membrane bioreactor, Process Biochemistry, 41(8), 1751–1757.
Gholami, M.; Nasseri, S.; Alizadehfard, M. R.; Mesdaghinia, A., (2003). Textile dye removal by membrane technology and biological oxidation, Water Qual. Res., 38(2), 379–391.
Hong, S.; Elimlech, M., (1997). Chemical and physical aspects of natural organic matter (NOM) fouling of nanofiltration membranes. J. Membr. Sci., 132(2), 159–181.
Jucker, C.; Clark, M. M., (1994), Adsorbtion of aquatic humic substances on hydrophobic ultrafiltration membranes. J.Membr. Sci., 97(1–3), 37–52.
Kim, T.; Park, C., (2005), Water recycling from desalination and purification processes of reactive dye manufacturing industry by combined membrane filtration, Cleaner Prod., 13(8), 779–786.
Koyuncu, I., (2002). Reactive dye removal in dye/salt mixtures by nanofiltration membranes containing vinylsulphone dyes: Effects of feed concentration and cross flow velocity. Desalination, 143(1–3), 243–253.
Koyuncu, I.; Topacik, D., (2002). Effects of organic ion on the separation of salts by nanofiltration membranes., J. Membrane Sci., 195(2) 247–263.
Koyuncu, I.; Topacik, D.; Wiesner, M. R., (2003). Factors influencing flux decline during nanofiltration of solutions containing dyes and salts. Water Res., 38(2), 432–440.
Ku, Y.; Lee, P.; Wang, W., (2005), Removal of acidic dyestuff in aqueous solution by nanofiltration, J. Membrane Sci., 250(1–2), 159–165.
Laine, J.; Hagstorm, J. P.; Clark, M.; Mallevialle, J., (1998), Effects of ultrafiltration membrane composition, J. Am. Water Works Assoc., 11(6), 61–67.
Lebrun, R.; Noel, I. M.; Bouchard, C. R., (2000). Electro-nanofiltration of a textile direct dye solution, Desalination, 129(1-3), 125–136.
Lee, H.; Amy, G.; Cho, J.; Yoon, Y.; Moon, S.; Kim, I. S., (2001). Cleaning strategies for flux recovery of an ultrafiltration membrane fouled by natural organic matter, Water Res., 35(14), 3301–8.
Lopez, A., (1999). Textile wastewater reuse: ozonation of membrane concentrated secondary effluent. Water Sci. Tech., 40(4–5), 99–105.
Moulin, P.; Allergre, C.; Maisseu, M.; Charbit, F., (2004). Saving and re-use of salts and water present in dye house effluents. Desalination, 162(1–3), 13–22.
Papic, S.; Kopivanac, N.; Ana, L. B.; Azra, M., (2004). Removal of some reactive dyes from synthetic wastewater by combined Al(III) coagulation / carbon adsorption process, Dyes and Pigment, 62(3), 291–298.
Rott, U.; Minke, R., (1999). Overview of wastewater treatment and recycling in the textile processing industry, Water Sci. Tech., 40(7), 137–144.
Tchobanoglous, G.; L. Burton, F.; D.Stensel, H., (2003). Wastewater engineering: treatment and reuse, fourth ed., Mc Graw Hill New York, USA.
Vander Burggen, B.; Daems, B.; Wilms D.; Vandecasteele, C., (2001). Mechanisms of retention and flux decline for the nanofiltration of dye baths from the textile industry. Sep. Purif. Tech., 22–23, 519–528.
Yuan, W.; Zydney, A. L., (1999). Humic acid fouling during microfiltration, J. Membrane Sci., 157(1), 1–12.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hassani, A.H., Mirzayee, R., Nasseri, S. et al. Nanofiltration process on dye removal from simulated textile wastewater. Int. J. Environ. Sci. Technol. 5, 401–408 (2008). https://doi.org/10.1007/BF03326035
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF03326035